Assessment of metals in ground water and surface water of different stations in and around Chopan river of Rahogarh, Madhya Pradesh has been carried out in the year (2004). The present work was conducted to evaluate four metals i.e. Copper, Iron, Zinc and Lead from four tube wells and six stations at Chopan river. It was found that the values of Iron metal were higher at some stations particularly near the study area i.e. Fertilizer industry.