当前世界环境

Introduction

煤矿行业现在使用现代科技with powerful and high capacity machinery so as to increase coal extraction capability at the cost of large amount of dust, gases, etc. spewed into the atmosphere, thereby degrading quality of air. These pollutants have harmful consequences not only on the mine workers, but also, depending on the meteorological conditions, on the human settlements, agricultural lands and live stocks in the nearby areas.

Particulate matter is the predominant pollutant connected with the coal mining and its handling operations. The airborne particulates and the associated trace metals were found to be the major cause of both acute and chronic adverse health effects (Prieditis and Adamson, 2002; Magas et al., 2007; Wild et al., 2009). A number of epidemiological studies indicated a significant linkage between airborne particulate matters and elevated rate of mortality (Pope, 2000; Shah, 2009). The techniques of coal extraction and processing are very specific to the individual site due to difference in geology, mineralogy, terrain and many other factors. Through this research study, emphasis has been made to provide salient information/features of air quality aspects in an open cast mine of Jharia Coalfield.

Description of study area

Rajapur OCP (open cast project) is one of the important OCP in Cluster VII of Bharat Coking Coal Ltd (BCCL) in Jharia Coalfield (Fig 1).BCCL which is a subsidiary of Coal India Limited operates in the state of Jharkhand and West Bengal. Its operation is spread over 305 Km²in the districts of Dhanbad, Bokaro and Burdwan. Mining operation is spread over two coalfields namely Jharia Coalfield and Ranigunj Coalfield. BCCL has produced 29.04 Mt. of coal during 2010-11. Cluster VII covers 12 mining lease holds with 14 underground/opencast mines. The total leasehold of this Cluster is 2127.70 Ha. It is located in the East Central part of JCF. It falls between the latitude 23⁰47’ 00” to 23⁰43’ 10’’ N and longitudes 86⁰22’ 54.6’’ to 86⁰24”45大肠火的集群有悠久的历史nd subsidence.

无花果ure 1: Site map of Jharia Coalfield Click here to View figure

Materials and methodology

Ambient air quality monitoring was undertaken at Rajapur OCP of Jharia coalfield during Summer, 2014. The sampling was done for twenty four hours and twice a week and it was continued for four weeks in summer season as per the criteria of IS 5158 Part-XIV, 2006.

Sampling for estimation of SPM and PM₁₀concentrations were performed with the help of Respirable Dust Sampler with thermo-electrically cooled gaseous sampler attachment (Envirotech make). The flow rate of the sampler was maintained at 1.1-1.3 m³/min for respirable particulate matter and 0.5 and 0.2 lpm for SO₂and oxides of nitrogen (NOx) respectively. The respirable dust sampler (APM 460 NL) uses an enhanced model of cyclone to separate the coarser particles from the air stream before filtering it on the 0.5 micron glass-fiber pore-size filter which allows a determination of both SPM and the respirable fraction of suspended particulate matter (RPM). The coarse particles collected in the cyclone separator are transferred quantitatively on a petridish and evaluated gravimetrically. Sum of masses of coarse and respirable particles gives the mass of SPM collected during sampling. The SPM concentrations are computed from the mass of SPM and total volume of air sampled. Similarly, for PM_2.5,APM 560 Fine Dust Sampler (16.7 LPM) was used. Here, ambient air is allowed to pass through Louvered inlet and WINS Impactor assembly. Particulate matter of size <2.5 microns is deposited on 46.2 mm dia. PTFE filter paper. The difference of final weight and initial weight of filter paper gives the weight of particulate matter of size <2.5 microns. The concentration of PM_2.5计算重量的灰尘沉积在吗filter divided by volume of air sampled.The samplers were installed in the field as per the prescribed sampling siting criteria of IS: 5182 part IV giving a special emphasizes on machine safety and power availability. For analysis of trace metals in ambient air was done according to standard methodology. The acid digestion was performed in Teflon bombs. The filtrates were analyzed using AAS (GBC Avanta) for determination of trace metals. The detection limit for different trace metals for the AAS are as follows Fe (0.005 ppm), Pb (0.01 ppm), Ni (0.009 ppm), Zn (0.005 ppm), Cu (0.001 ppm, Cd (0.004 ppm), Mn 90.0015 ppm) and Cr 90.003 ppm).The concentration of an element in the atmosphere is obtained from the following relation,

C(μg/m3) = Concentration of the element in digested sample (μg/mL)/volume of the air sample(m³) x Total volume of the sample (mL)/Percent of filter area used for analysis.

Results and Discussions

The average concentration of SPM, PM₁₀and PM_2.5concentrations were observed in the range of 294 to 965μg/m³, 100 to 498 μg/m³and 85 to 296 μg/m³分别。SO₂and NOx concentration were in the range of 48.2 to 98.2μg/m³and 32.8 to 149.39 μg/m³分别。The air quality data are depicted in Table 1. The observed concentrations were then compared with National ambient air quality standard (NAAQS, 2009). Ambient Air quality Standard for existing as well as new Coal Mines (CMS, 2000) laid down and notified by MOEF, GOI in September 2000 was also considered to evaluate the pollution status. The comparisons are presented in Fig 2 to Fig 6.The average PM₁₀concentration exceeded both NAAQS (100 μg/m³) and CMS (300 μg/m³). The high concentration of PM₁₀is mainly due to different mining activities as well as running of vehicles on the unpaved road including abrasion of road materials, tires and brake linings as well as re-suspension of soil material because of traffic induced turbulence (Barmpadimos et al., 2011; Bukowiecki et al., 2010).The PM_2.5concentration exceeded NAAQS (60 μg/m³).The sources of PM_2.5has generally been confined to movement of vehicle on paved/unpaved roads, vehicular exhaust (diesel based), mining activities particularly drilling and blasting of rocks. The emission inventory indicates that heavy duty diesel trucks were accountable for majority of the exhaust particulate matter(Sawyer et al., 2000).The SPM concentration exceeded permission level of CMS (600 μg/m³). The movement of vehicles on the haul road of the opencast mines has been recognized as the major source of fugitive dust emitted from the surface coal mines (Cowherd, 1979). The average SO₂concentration was below NAAQS (80 μg/m³) and CMS (120 μg/m³). The same for NO_Xwas found above NAAQS (80 μg/m³) but below CMS (120 μg/m³). The main source of NOx in coal mining rejoin are vehicular exhaust, blasting operations, etc. Unpremeditated burning of coal in waste dumps and mine fire release considerable amount of oxides of nitrogen. During combustion process (at high temperature) atmospheric nitrogen combines with oxygen to form NO_Xwhich is aggravated when engine is diesel operated. Tunnel studies indicated that diesel engine produce five times the amount of NO_Xper mass of fuel burned when compared to gasoline vehicles (Kirchstetter et al., 1998).

Table 1: Air Quality Data

Parameters	SPM	PM10	PM2.5	SO2	NOx
No. of observations	24	24	24	24	24
Minimum Concentration(μg/m3)	294	100	85	48.2	32.8
Maximum Concentration(μg/m3)	965	498	296	98.2	149
Average	743.875	333.2	160.91	79.47	111.39
98th percentile	957.18	492.02	288.18	97.64	148.43

Table 2: Trace elements concentration level in summer season

Trace Metal	Concentration inµg/m3
Pb	0.380 ± 0.009
Ni	0.06 ±0.02
As	0.00432±0.028
Cu	3.10 ± 0.01
Mn	1.52 ± 0.21
Fe	18.29 ± 0.25
Zn	0.42 ± 0.24
Cd	0.04 ± 0.016
Cr	0.440 ± 0.30

无花果ure 2: Status of PM10in comparison with NAAQS,2009 and CMS, 2000 Click here to View figure

无花果ure 3: Status of PM2.5in comparison with NAAQS, 2009 Click here to View figure

无花果ure 4: Status of SPM in comparison with CMS, 2000 Click here to View figure

无花果ure 5: Status of SO2in comparison with NAAQS, 2009 and CMS,2000 Click here to View figure

无花果ure 6: Status of NOXin comparison with NAAQS, 2009 and CMS,2000 Click here to View figure

Trace elements analysis of dust samples (PM₁₀) during summer season were done and shown in Table 2.Trace element pollutants in PM₁₀may be natural or anthropogenic. Several trace elements (Pb, Cu, Mn, Co) are considered essential for life. The sources of trace elements may be attributed as discussed below:

Pb (Lead): may be due to higher emissions from vehicular exhausts. This does not rule out the case of adulteration of fuel for automobiles.

Ni (Nickel): may be due to traffic exhausts, wearing and tearing of vehicular engines parts for old vehicles, etc.

As(Arsenic):Arsenic compounds can be either organic or inorganic. Inorganic arsenic can cause acute, sub acute and chronic effects, which may be either chronic or systematic.

Cu (Copper): this originates from wearing of brake pads of vehicles due to forced deceleration (Hulskotte et al., 2006).

Mn (Manganese): this may be due to crustal dust which includes the suspension of road dusts by vehicles and wind erosion .

Fe (Iron): This is due to the use of iron in brake lining which leads to its emission in ambient air. (Hulskotte et al., 2006)

Zn (Zinc): This is due to tracer of tire wear particles from vehicular movement (Birmili et al., 2006; Wang et al., 2006)

Cd (Cadmium): Cd level may be related due to the composition of gasoline, motor oil, car tires and road side deposition of the residues of those materials as well as traffic density (Sharma and Prasad,2010)

Cr (Chromium): Chromium is emitted mainly by fumes stainless steel welding (WHO.2000; Langard,1994; Danielsen et al.,1993) and from the abrasion of brake lining and tire of the vehicles (Sadasivan and Negi,1900;Hopke,1980).

观察到的浓度n compared with National ambient air quality standard (NAAQS, 2009) (Fig 7-9).The measured concentration of Ni (0.06µg/ m³) was found more than NAAQS limit concentration (0.02 µg/m³) whereas measured concentration of Arsenic and lead ( 4.320 ng/m³and 0.380 µg/ m³respectively) was found considerably less than NAAQS concentration 6.0 ng/m³and 1.0 µg/m³分别。

无花果ure 7: Status of Pb in comparison with NAAQS, 2009 Click here to View figure

无花果ure 8: Status of Ni in comparison with NAAQS, 2009 Click here to View figure

无花果ure 9: Status of As in comparison with NAAQS, 2009 Click here to View figure

Conclusion

The study reveals the generation of considerable amount of particulate matters due to various mining activities of the concerned opencast mine of the Jharia coalfield. The measured concentration of the particulate matter (SPM, PM₁₀and PM_2.5) exceeded the NAAQS, 2009 and CMS, 2000 standards. Among heavy metals, observed concentration of Ni was found more than NAAQS limit due to vehicular exhausts, wearing and tearing of vehicular engine parts, etc. However, the concentration of Arsenic and lead was found within the permissible limit. The trace metals concentrations were observed as per following decreasing trend, Fe> Cu> Mn> Cr> Zn> Pb>Ni>Cd> As. For the lack of any existing guidelines, the concentrations of other trace metals could not be compared.

Acknowledgment

The authors would like to thank the Department of Environmental science and Engineering of Indian School of Mines, Dhanbad for providing necessary facilities to undertake the present research study. We are also thankful to Bharat Coking Coal Ltd for their support and encouragement.

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